Analytical Method Reports by EURL-SRM
In the table below you will find a collection of methods concerning pesticides that are traditionally either not amenable to multiresidue methods or difficult to analyze.
Further information
» EURL-SRM Strategy on the developement and validation of methods for SRM-compounds
» Website with links to Method-Collections of all 4 EURLs
» List of Reports about Analytical Observations made by the EURL-SRM
Methods for individual SRM-compounds
| Analyte | Abbreviation used in Method-List | Short description | Full Paper |
|---|---|---|---|
| 4-Hydroxy-Chlorothalonil | SRM-10 | Go to "Chlorothalonil, 4-Hydroxy" | |
| Abamectin | SRM-01 | Analysis of Abamectin via QuEChERS and LC-MS/MS | Link |
| Acidic Pesticides | SRM-02 | Acidic pesticides in food of plant origin see List of Observations |
|
| Acidic Pesticides (in Milk) |
SRM-03 | Acidic pesticides in milk (via modified QuEChERS) A procedure for esters and conjugates is described in document SRM-43. |
Link |
| Acidic Pesticides (in cereals following Alkaline Hydrolysis) |
SRM-04 | Analysis of Phenoxy Alkanoic Acids in Cereals (via QuEChERS including Optional Alkaline Hydrolysis module). This method is obsolete, please refer to document SRM-43, which also addresses the hydrolysis of hydrolysis-resistant esters. |
Link (see also SRM-43) |
| Amitraz | SRM-05 | Analysis of Amitraz and its Main Metabolite N-2,4-Dimethylphenyl-N-Methylformamidine in pears via QuEChERS and LC-MS/MS | Link |
| Amitrole | SRM-09 | See QuPPe method | |
| Azocyclotin | SRM-16 | The previous method document was incorporated in the new Observations Document | Link |
| Benfuracarb | SRM-23 | Analysis of Residues of Carbofuran (sum) Using QuEChERS Method. See also SRM-33 document in the List of Observations | Link |
| Bifenazate, Bifenazate-diazene |
SRM-34 | Analysis of Bifenazate (sum) by QuEChERS Method using LC-MS/MS Last update: 17.03.2017 (V1) |
Link |
| Bromide, Total Inorganic | SRM-06 | Bromine containing fumigants determined as Total Inorg. Bromide following derivatisation with propylene oxide, partitioning in ethyl acetate and GC analysis. Last update: 11.09.2008 For the analysis of bromide ion via LC-MS/MS please refer to the QuPPe method (SRM-09) |
Link |
| Captan | SRM-07 | Quantification of Residues of Folpet and Captan in QuEChERS Extracts See List of Observations See also excel documents for the calculation of Captan and THPI. a) using external calibration b) using standard additions Last update: 04.04.2017 |
|
| Carbofuran | SRM-23 | Analysis of Residues of Carbofuran (sum) Using QuEChERS Method. See also SRM-33 document in the List of Observations | Link |
| Carbosulfan | SRM-23 | Analysis of Residues of Carbofuran (sum) Using QuEChERS Method. See also SRM-33 document in the List of Observations | Link |
| Chlorate | SRM-09 | See QuPPe method | |
| Chloridazon-desphenyl | SRM-51 | Analysis of chloridazon-desphenyl in case of interfering matrix in LC-MS/MS to avoid false positives, e.g. in honey; see List of Observations also see QuPPe method |
|
| Chlormequat and Mepiquat | SRM-08 and SRM09 | Analysis of Chlormequat and Mepiquat Residues in Foods of Plant Origin; Last update: 10.01.2009 (V2) also see QuPPe method |
Link |
| Chlorothalonil | SRM-10 | Modified QuEChERS-Method for the Analysis of Chlorothalonil in Fruits and Vegetables |
Link |
| 4-OH-chlorothalonil (SDS-3701) in Milk |
SRM-28 | Analysis of 4-Hydroxy-Chlorothalonil (SDS-3701) in Milk. Analysis in fruits and vegetables -> see under "Chlorothalonil" |
Link |
| Cyhalothrin, Lambda- / Gamma- |
SRM-39 | A QuEChERS-based procedure involving enantioselective LC-MS/MS analysis of the two isomers of lambda-cyhalothrin is presented. Separation is achieved on a cellulose-based stationary phase covered by an immobilized chiral selector. Last update: 12.04.2019 (V1) |
Link |
| Cyromazine | SRM-09 | See QuPPe method | |
| Cyhexatin | SRM-16 | The previous method document was incorporated in the new Observations Document | Link |
| Daminozide | SRM-09 | See QuPPe method | |
| Dicofol | SRM-11 | See List of Observations | |
| Diethanolamine | SRM-09 | See QuPPe method | |
| Difenzoquat and N,N-Dimethylhydrazine | SRM-09 | See QuPPe method | |
| Diquat | SRM-09 | See QuPPe method | |
| Dithianon | SRM-12 | Analysis of Dithianon in Fruits and Vegetables using acidified QuEChERS and LC-MS/MS. Last update: 29.04.2016 See also the respective analytical observations report with background information on this method (SRM-13) |
Link |
| Dithiocarbamates as CS2 | SRM-14 | See List of Observations | |
| Dodine | SRM-15 | See List of Observations | |
| Ethephon | SRM-09 | See QuPPe method | |
| Ethoxyquin | SRM-21 (Plant origin), SRM-24 (Animal origin) | See List of Observations | |
| ETU | SRM-09 | See QuPPe method | |
| Fenbutatin oxide | SRM-16 | The previous method document was incorporated in the new Observations Document | Link |
| Fentin | SRM-16 | The previous method document was incorporated in the new Observations Document | Link |
| Flonicamid Metabolites (TFNA, TFNG, TFNA-AM) | SRM-17 | Validation of Flonicamid-Metabolites (TFNA, TFNG, TFNA-AM) using QuEChERS method | Link |
| Fluoride ion | SRM-50 | Determination of fluoride ion with direct measurement and/or following microdiffusion using ion selective electrodes (ISE) See List of Observations |
|
| Fosetyl Aluminium (detected as Fosetyl) | SRM-09 | See QuPPe method | |
| Folpet | SRM-07 | Quantification of Residues of Folpet and Captan in QuEChERS Extracts See List of Observations See also excel documents for the calculation of Captan and THPI. a) using external calibration b) using standard additions Last update: 06.04.2017 |
|
| Fumigants | SRM-29 | Analysis of fumigants in cereals and dry fruits by applying GC-MS/MS determination. The following compounds are included: trichloroethylene, ethylene chlorobromide, 1.3-dichloropropene (cis+trans), tetrachloroethylene, 1,1,2,2-tetrachloroethane, p-dichlorobenzene, naphthalene, 1.2-dibromo-3-chloropropane, dichlorvos, p-nitrochlorobenzene, azobenzene, chloropicrin and ethylene dibromide |
Link |
| Furathiocarb | SRM-23 | Analysis of Residues of Carbofuran (sum) Using QuEChERS Method. See also SRM-33 document in the List of Observations | Link |
| Glufosinate | SRM-09 | See QuPPe method | |
| N-Acetyl glufosinate | SRM-09 | See QuPPe method | |
| MPPA (glufosinate metabolite) |
SRM-09 | See QuPPe method | |
| Glyphosate | SRM-09 | See QuPPe method | |
| N-Acetyl-glyphosate (glyphosate metabolite) | SRM-09 | See QuPPe method | |
| AMPA (glyphosate metabolite) |
SRM-09 | See QuPPe method | |
| N-Acetyl-AMPA (glyphosate metabolite) | SRM-09 | See QuPPe method | |
| HEPA (ethephon metabolite) |
SRM-09 | See QuPPe method | |
| Kasugamycin | SRM-09 | See QuPPe method | |
| Maleic hydrazide | SRM-09 | See QuPPe method | |
| Mepiquat | SRM-09 | See QuPPe method | |
| Meptyldinocap | SRM-47 | See List of Observations | |
| Morpholin | SRM-09 | See QuPPe method | |
| Nereistoxin | SRM-09 | See QuPPe method | |
| Nicotine | SRM-30 | Analysis of Nicotine in Mushrooms using QuEChERS under alkaline conditions | Link |
| Organotins | SRM-16 | The previous method document was incorporated in the new Observations Document | Link |
| Paraquat | SRM-09 | See QuPPe method | |
| PCP | SRM-31 | Analysis of Pentachlorophenol (PCP) in guar gum by modified QuEChERS method; Link to Commission Decision of 29 April 2008 imposing special conditions governing guar gum originating in or consigned from India due to contamination risks of those products by pentachlorophenol and dioxins: 2008/352/EC | Link |
| Perchlorate | SRM-09 | See QuPPe method | |
| Phosphine | SRM-18 | Analysis of the Fumigant Phosphine by applying Headspace-GC-MSD | Link Link |
| Phosphonic acid (plant strengthener and Fosetyl degradant) | SRM-09 | See QuPPe method | |
| Prochloraz | SRM-19 | See List of Observations | |
| Propamocarb | SRM-20 | See List of Observations | Link |
| Propineb, Propylene diamin | SRM-48 | See List of Observations | Link |
| PTU | SRM-09 | See QuPPe method | |
| Pyridate | SRM-22 | See List of Observations | |
| Pymetrozine | SRM-32 | See List of Observations | |
| QAC (DDAC C10, BAC-C8, C10, C12, C14, C16, C18) |
SRM-26 | Analysis of Didecyldimethylammonium chloride (DDAC-C10) and Benzalkonium chloride (BAC-C10; BAC-C12; BAC-C14; BAC-C-16) by applying the QuEChERS method without cleanup and LC-MS/MS determination (ESI-positive mode). Last update: 23.02.2023 (V6) |
Link |
| QACs (in Milk) (DDAC C10, BAC-C10, C12, C14, C16) |
SRM-27 | Analysis of DDAC-C10 and BAC (BAC-C10; BAC-C12; BAC-C14; BAC-C-16) in milk by applying the QuEChERS method without cleanup and LC-MS/MS determination (ESI-positive mode). | Link |
| Streptomycin | SRM-09 | See QuPPe method | |
| Triazole Derivative Metabolites (TDMs) | SRM-09 | See QuPPe method See also Publication "Determination of Triazole Derivative Metabolites (TDMs) in Fruit and Vegetables using the QuPPe Method and Differential Mobility Spectrometry (DMS) and Survey of the Residue Situation in Organic and Conventional Produce" |
Link |
| Triethanolamine | SRM-09 | See QuPPe method | |
| Trimesium (trimethylsulfonium cation) | SRM-09 | See QuPPe method |
Additional documents on analytical topics
Strategy of EURL-SRM method development activities
Impact of various factors on the extractability of incurred pesticide residues
Collection of Analytical Observations
Excel file for the calculation Captan/THPI and Folpet/Phthalimide using external calibration
(see Description of Procedure)
Excel file for the calculation Captan/THPI and Folpet/Phthalimide using standard additions
Last update: 06.04.2017
(see Description of Procedure)
Workflow to perform quantification by standard addition procedure
Standard addition is an effective way to compensate for matrix effects, e.g. in cases of "difficult" matrix-pesticide combinations or if no blank matrix is available for external matrix matched calibration. Standard addition can be performed either to aliquots of the sample extract or direct to analytical portions prior to extraction. In the first case, it only corrects for matrix effects as well as for analyte degradation in the extract, the latter case, it also corrects for recovery during extraction and clean-up. Because of linear extrapolation linearity of response throughout the measured concentration range is paramount. Furthermore it should be considered, that added amounts are not too small in order to reduce the influence of measurement variability on the slope of the linear regression.
Excel file Standard Addition to Extract Aliquots
Excel file Standard Addition to Sample Portions
Last modified 19-11-2024, 19:10:56
Published 25-04-2016, 08:18:21
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